Distribution and influencing factors of atmospheric nitrogen oxides (NOx) over the east coast of China in spring: Indication of the sea as a sink of the atmospheric NOx.

An integrated observation of NOx that included coastal cities and oceanic cruises covering the Qingdao coastal waters sites (QDCW) and the Yellow Sea and East China Sea sites (YECS) was conducted in spring. The average concentrations of the coastal cities, the QDCW, and the YECS were 5.4 ± 4.1, 4.2 ± 3.5, and 2.9 ± 6.8 ppb for NO while 18.5 ± 7.2, 9.4 ± 5.2, and 4.9 ± 6.4 ppb for NO2, depicting lowest levels in the open seas. Atmospheric NO and NO2 showed similar spatial variations over the seas, the stations where the air masses originated from land or nearshore regions showed higher levels, but the decisive influencing factors were not the same in the different study areas. The calculated NOx flux value in the YECS (-8.7 × 10-17 mol N cm-2) indicated that the sea surface was a net sink of atmospheric NOx.

Distribution, sources, and eco-risk of Current-Use Pesticides (CUPs) in the coastal waters of the northern Shandong Peninsula, China.

This study investigated the spatial distributions and seasonal variations of 19 CUPs in the coastal areas of the Shandong Peninsula and its surrounding rivers and assessed their ecological risk. In freshwater and seawater, insecticides (chlorpyrifos, methoxychlor, and pyridaben), as well as fungicides (fenarimol) and herbicides (dichlobenil) were the main pollutants (Detection Frequency: 100 %). Spatially, during winter, the regional pollution levels of Σ19CUPs in seawater showed a trend of Laizhou Bay (LZB, mean:4.13 ng L-1) > Yellow River Estuary (YRE, mean:2.57 ngL-1) > Bohai Bay (BHB, mean:2.21 ng L-1) > Yanwei Area (YWA, mean:1.94 ng L-1). The similarities of major substances between rivers and the marine environment suggest that river discharge is the main source of CUPs pollution in coastal areas. In summer, CUPs in rivers posed a high risk. In winter, the risk significantly decreased, indicating a moderate overall risk. Seawater exhibited a low risk in winter.

Enterococci pathways to coastal waters and implications of sea level rise.

Highly urban coastal communities in low lying areas and with high water tables are vulnerable to sea-level rise and to corresponding increases in coastal groundwater levels. Stormwater conveyance systems are under increased risk. Rising groundwater levels affect the hydraulics of the stormwater system thereby increasing contaminant transport, for example the fecal indicator bacteria enterococci, to coastal waters. This study offers a unique opportunity to evaluate the impacts of increased contaminant transport on marine coastal environments. Here we assessed historic and recent coastal water quality, stormwater sampling data, groundwater monitoring and tidal elevations near the coastline, in the context of altered hydraulics within the system. Two pathways of enterococci to marine waters were identified. Direct discharge of contaminated stormwater runoff via the stormwater outfalls and tidally driven contaminated groundwater discharge. As sea level continues to rise, we hypothesize that a diminished unsaturated zone coupled with altered hydraulic conditions at the coastal groundwater zone will facilitate the transport of enterococci from urban sediments to the study site (Park View Waterway in Miami Beach, FL USA). We recommend improvements to the stormwater conveyance system, and maintenance of the sanitary sewer system to mitigate these impacts and minimize transport of enterococci, and other stormwater pollutants to coastal waters. The results of this study can be useful to interpret high enterococci levels in low lying coastal areas where groundwater is influenced by rising sea water levels.

Too hot to handle? An urgent need to understand climate change impacts on the biogeochemistry of tropical coastal waters.

Tropical regions contain ecologically and socio-economically important habitats, and are home to about 3.8 billion people, many of which directly depend on tropical coastal waters for their well-being. At the basis of these ecosystems are biogeochemical processes. Climate change is expected to have a greater impact in the tropics compared to temperate regions because of the relatively stable environmental conditions found there. However, it was surprising to find only 660 research articles published focusing on the impact of climate change on the biogeochemistry of coastal tropical waters compared to 4823 for temperate waters. In this perspective, we highlight important topics in need of further research. Specifically, we suggest that in tropical regions compared to temperate counterparts climate change stressors will be experienced differently, that organisms have a lower acclimation capacity, and that long-term baseline biogeochemical datasets useful for quantifying future changes are lacking. The low number of research papers on the impacts of climate change in coastal tropical regions is likely due to a mix of reasons including limited resources for research and limited number of long time series in many developing tropical countries. Finally, we propose some action points that we hope will stimulate more studies in tropical coastal waters.

Spatial variability of aragonite saturation state (Ωarag) in Indonesian coastal waters.

The effects of Ocean acidification (OA) on the coastal waters of small islands in Indonesia have yet to be extensively studied. This research aims to investigate the process of OA in the coastal waters of small Indonesian islands and examine how land-sea interactions impact carbonate mineral saturation. We collected seawater samples from seven locations on small islands in Indonesia between 2015 and 2021 to analyze the aragonite saturation state. The result shows that most of Indonesia's coastal waters are accompanied by supersaturation of aragonite saturation state (Ωarag>1). Selayar Island's waters had the highest aragonite saturation, averaging 4.96 ± 0.48, while Pari Island's coastal waters had the lowest, averaging 2.49 ± 0.50. Salinity had the greatest effect on Ωarag in all of the sampling sites, ranging from 24.13% to 52.92%, except Aceh Island, where temperature had a greater impact (34.35%) than salinity (26.99%). By the end of this century, Ωarag is predicted to decline based on projections related to climate change. Small island coastal waters are expected to experience a more substantial decline compared to those near the mainland, ranging from 4.71% to 79.58%. The coastal waters of Weh and Selayar Island are probably going to decline the greatest, while the coastal waters of Sorong (mainland) are probably going to decline the least. All seven sampling locations are expected to observe the decrease. This decline will be observed at all seven sampling locations, with Ωarag values ranging from 1.91 to 3.35.

New insights into estimation of bioavailable inorganic phosphorus in natural coastal seawater.

Considering the impact of the high salinity and high turbidity of coastal seawater on phosphorus forms, a new method was proposed to determine bioavailable inorganic phosphorus (BIP). The phosphorus most relevant to eutrophication is BIP, and traditional analysis methods may underestimate the degree of eutrophication. In this study, a microelectrode of multigold (AuµE) was fabricated for direct voltammetric determination of BIP without filtration, and BIP environmental characteristics including distribution and correlation relationships with environmental factors in typical coastal seawater of Northern China were analyzed. The proposed AuµE showed a low detection limit of 0.03 µM. The surface and bottom BIP concentrations ranged from 1.00 to 2.13 and from 0.88 to 2.05 µM, respectively. BIP dominated the total P (TP) accounting for 48.5-67.5 % in the surface layer samples, and 32.6-92.7 % in the bottom layer samples, respectively. The concentrations of BIP were obviously higher than those of DIP, indicating that DIP may underestimate the probability of eutrophication occurring. And BIP was positively correlated with dissolved oxygen (DO) (P < 0.05). BIP may be a promising indicator of eutrophication potential in coastal areas with high salinity and high turbidity. The proposed reliable voltammetry method provides a new indicator for environmental assessment and represents a significant step in the comprehensive analysis of P species.

Long-term trends in juvenile Mugil liza abundance in relation to selected environmental and fisheries influences in southern Brazil.

Overfishing constitutes a major threat affecting marine fish population worldwide, including mullet species that have been exploited by fisheries during the reproductive migration in temperate and tropical latitudes for millennia. In the present study, we investigated the relationship of fishing intensity of mullet Mugil liza during its reproductive migration and the abundance of their juveniles in an essential nursery ground for the species in the southwest Atlantic Ocean. To carry out this analysis, we used a 23-year standardized long-term time series (1997-2019) of monthly abundance of M. liza juveniles, local/regional (water temperature, salinity, water transparency and river discharge) and global (ENSO) environmental factors, along with compilations of fishing landing data for the species. Generalized Additive Models (GAM) revealed the negative effect of fishing adult populations on the abundance of juveniles when they reach the marine surf-zone and after recruiting into the estuary. Our results reinforce the importance of adequate conservation and fishery regulation policies to prevent the species' stock from collapsing.

Causes of coastal waters pollution with nutrients, chemicals and plastics worldwide.

Worldwide, coastal waters contain pollutants such as nutrients, plastics, and chemicals. Rivers export those pollutants, but their sources are not well studied. Our study aims to quantify river exports of nutrients, chemicals, and plastics to coastal waters by source and sub-basin worldwide. We developed a new MARINA-Multi model for 10,226 sub-basins. The global modelled river export to seas is approximately 40,000 kton of nitrogen, 1,800 kton of phosphorous, 45 kton of microplastics, 490 kton of macroplastics, 400 ton of triclosan and 220 ton of diclofenac. Around three-quarters of these pollutants are transported to the Atlantic and Pacific oceans. Diffuse sources contribute by 95-100 % to nitrogen (agriculture) and macroplastics (mismanaged waste) in seas. Point sources (sewage) contribute by 40-95 % to phosphorus and microplastics in seas. Almost 45 % of global sub-basin areas are multi-pollutant hotspots hosting 89 % of the global population. Our findings could support strategies for reducing multiple pollutants in seas.

Foraging behavior and sea ice-dependent factors affecting the bioaccumulation of mercury in Antarctic coastal waters.

To elucidate the potential risks of the toxic pollutant mercury (Hg) in polar waters, the study of accumulated Hg in fish is compelling for understanding the cycling and fate of Hg on a regional scale in Antarctica. Herein, the Hg isotopic compositions of Antarctic cod Notothenia coriiceps were assessed in skeletal muscle, liver, and heart tissues to distinguish the differences in Hg accumulation in isolated coastal environments of the eastern (Chinese Zhongshan Station, ZSS) and the antipode western Antarctica (Chinese Great Wall Station, GWS), which are separated by over 4000 km. Differences in odd mass-independent isotope fractionation (odd-MIF) and mass-dependent fractionation (MDF) across fish tissues were reflection of the specific accumulation of methylmercury (MeHg) and inorganic Hg (iHg) with different isotopic fingerprints. Internal metabolism including hepatic detoxification and processes related to heart may also contribute to MDF. Regional heterogeneity in iHg end-members further provided evidence that bioaccumulated Hg origins can be largely influenced by polar water circumstances and foraging behavior. Sea ice was hypothesized to play critical roles in both the release of Hg with negative odd-MIF derived from photoreduction of Hg2+ on its surface and the impediment of photochemical transformation of Hg in water layers. Overall, the multitissue isotopic compositions in local fish species and prime drivers of the heterogeneous Hg cycling and bioaccumulation patterns presented here enable a comprehensive understanding of Hg biogeochemical cycling in polar coastal waters.

Habitat sensitivity in the West African coastal area: inferences and implications for regional adaptations to climate change and ocean acidification.

This study focuses on assessing coastal vulnerability and habitat sensitivity along the West African coast by delineating hotspots based on surface temperature, pH, chlorophyll-a, particulate organic carbon, and carbonate concentrations between 2018 and 2023 depending on data availability. Initial exploration of these variables revealed two distinct focal points i.e., the Togo-Nigerian coastal stretch and the stretch from Sierra Leone to Mauritania. Lower pH trends (acidification) in surface waters were observed off the West African coast, particularly in areas around the south-south Niger Delta in Nigeria and the coastal regions of Guinea and Guinea Bissau. Sea surface temperature analysis revealed highest temperatures (27-30°C) within Nigeria to Guinea coastal stretch, intermediate temperatures (24-27°C) within the Guinea Bissau and Senegal coastal stretch, and the lowest temperatures off the coast of Mauritania. Furthermore, correlation analysis between sea surface temperature and calcite concentration in the Mauritania-Senegal hotspot, as well as between overland runoff and particulate organic carbon in the Togo-Nigeria hotspot, revealed strong positive associations (r>0.60) and considerable predictive variability (R2 ≈ 0.40). From the habitat sensitivity analysis, certain regions, including Cape Verde, Côte d'Ivoire, Nigeria, Senegal, and Sierra Leone, exhibited high sensitivity due to environmental challenges and strong human dependence on coastal resources. Conversely, Gambia, Guinea, Guinea-Bissau, Liberia, and Togo displayed lower sensitivity, influenced by geographical-related factors (e.g. coastal layout, topography, etc.) and current levels of economic development (relatively lower industrialization levels). Regional pH variations in West African coastal waters have profound implications for ecosystems, fisheries, and communities. Addressing these challenges requires collaborative regional policies to safeguard shared marine resources. These findings underscore the link between ecosystem health, socioeconomics, and the need for integrated coastal management and ongoing research to support effective conservation.

Preliminary assessment of carbonic acid dissociation constants: Insights from observations in China's east coastal oceans.

Based on observations in China's east coastal oceans, we conducted a preliminary assessment of 16 sets of carbonic acid dissociation constants (K1* and K2*) by comparing spectrophotometrically measured pH values at 25 °C with those calculated from total alkalinity and dissolved inorganic carbon. We obtained that K1* and K2* often performed differently within different salinity ranges, and that the constants of Millero et al. (2002) (M02) demonstrated the best performance for the salinity range of 24-35. In contrast, the often recommended constants of Mehrbach et al. (1973) refit by Dickson and Millero (1987) (DM87-M) and Lucker et al. (2000) (L00) would underestimate pH at salinities of 24-30. This was mainly associated with the higher product of K1* and K2* by DM87-M and L00 than by M02 at this salinity range. Also, we found almost no differences between pH values calculated with DM87-M and L00.

A dinoflagellate bloom caused by multiple species of Kareniaceae in the coastal waters of Fujian in June 2022 and its adverse impacts on Brachionus plicatilis and Artemia salina.

Recently, dinoflagellate blooms have frequently occurred in the coastal waters of Fujian, East China Sea. In June 2022, a fish-killing bloom of Kareniaceae species occurred in this region. In this study, four species of Kareniaceae, namely, Karenia longicanalis, K. papilionacea, Karlodinium veneficum, and Karl. digitatum were identified from this bloom event based on the results of single-cell PCR and clone libraries, and intraspecies genetic diversity was found in the Karl. veneficum population. The results of acute toxicity assays of the bloom water to two zooplankton species (Brachionus plicatilis and Artemia salina) demonstrated this bloom event strongly inhibited their swimming capacities and survival. The results of this study suggested that the bloom events caused by multiple species of Kareniaceae in the Fujian coastal waters had adverse impacts on the local fishery resources and zooplankton community.

Occurrence and distribution of polycyclic aromatic hydrocarbons (PAHs) in marine organisms from Shenzhen coastal waters and human health risk assessment.

This study investigated the levels and composition of 16 priority polycyclic aromatic hydrocarbons (PAHs) in marine organisms from South China Sea and assessed their potential health risks. The results revealed that the pollution levels of total PAHs ranged from 3.56 to 392.21 ng/g dw. Notably, 4-ring PAHs constituted the predominant fraction (58.02 %) of the total PAHs, with pyrene being the most abundant congener across all species. Intriguingly, our findings suggested that consuming these organisms might pose a low non-cancer hazard. Nonetheless, benzo[a]pyrene was detected in most species, with levels ranging from non-detectable to 11.24 ng/g dw. The individual lifetime cancer risk levels associated with seafood consumption in studied regions ranged from 1.10 × 10-5 to 1.52 × 10-5, highlighting a potential cancer risk that warrants special attention. These findings emphasize the need to prioritize carcinogenic compounds over total PAHs and underscore the importance of continuous monitoring of PAH pollution in seafood.

Nutrients in overlying water affect the environmental behavior of heavy metals in coastal sediments.

Excessive nutrients in aquatic ecosystems are the main driving factors for eutrophication and water quality deterioration. However, the influence of nutrients in overlying water on sediment heavy metals is not well understood. In this study, the effects of nitrate nitrogen (NO3-N) addition and phosphate addition in the overlying water on the environmental behaviors of chromium (Cr), copper (Cu), and cadmium (Cd) in coastal river sediments were investigated. Fresh estuary sediments and synthetic saltwater were used in microcosm studies conducted for 13 d. To determine the biological effect, unsterilized and sterilized treatments were considered. The results showed that the diffusion of Cr and Cu was inhibited in the unsterilized treatments with increased NO3-N. However, under the NO3-N sterilized treatments, Cr and Cu concentrations in the overlying water increased. This was mostly related to changes in the microbial regulation of dissolved organic carbon and pH in the unsterilized treatments. Further, in the unsterilized treatments, NO3-N addition considerably increased the concentrations of the acid-soluble (Cr, Cu, and Cd increased by 5%-8%, 29%-41%, and 31%-42%, respectively) and oxidizable (Cr, Cu, and Cd increased by 10%, 5%, and 14%, respectively) fractions. Additionally, compared with that in the unsterilized treatments, Cu and Cd concentrations in P-3 treatments decreased by 7% and 63%, respectively. By producing stable metal ions, microorganisms reduced the amount of unstable heavy metals in the sediment and heavy metal concentration in the overlying water, by considerably enhancing the binding ability of phosphate and heavy metal ions. This study provides a theoretical basis for investigating the coupling mechanisms between heavy metals and nutrients.

Assessing the impact of COVID-19 lockdown on surface water quality in Ireland using advanced Irish water quality index (IEWQI) model.

The COVID-19 pandemic has significantly impacted various aspects of life, including environmental conditions. Surface water quality (WQ) is one area affected by lockdowns imposed to control the virus's spread. Numerous recent studies have revealed the considerable impact of COVID-19 lockdowns on surface WQ. In response, this research aimed to assess the impact of COVID-19 lockdowns on surface water quality in Ireland using an advanced WQ model. To achieve this goal, six years of water quality monitoring data from 2017 to 2022 were collected for nine water quality indicators in Cork Harbour, Ireland, before, during, and after the lockdowns. These indicators include pH, water temperature (TEMP), salinity (SAL), biological oxygen demand (BOD5), dissolved oxygen (DOX), transparency (TRAN), and three nutrient enrichment indicators-dissolved inorganic nitrogen (DIN), molybdate reactive phosphorus (MRP), and total oxidized nitrogen (TON). The results showed that the lockdown had a significant impact on various WQ indicators, particularly pH, TEMP, TON, and BOD5. Over the study period, most indicators were within the permissible limit except for MRP, with the exception of during COVID-19. During the pandemic, TON and DIN decreased, while water transparency significantly improved. In contrast, after COVID-19, WQ at 7% of monitoring sites significantly deteriorated. Overall, WQ in Cork Harbour was categorized as "good," "fair," and "marginal" classes over the study period. Compared to temporal variation, WQ improved at 17% of monitoring sites during the lockdown period in Cork Harbour. However, no significant trend in WQ was observed. Furthermore, the study analyzed the advanced model's performance in assessing the impact of COVID-19 on WQ. The results indicate that the advanced WQ model could be an effective tool for monitoring and evaluating lockdowns' impact on surface water quality. The model can provide valuable information for decision-making and planning to protect aquatic ecosystems.

[Distribution, Source, and Ecological Risk Assessment of Persistent Organic Pollutants in Surface Sediments of Boao Coastal Waters].

Persistent organic pollutants (POPs) in the environment have the characteristics of persistence, bioaccumulation, teratogenicity, carcinogenicity, and mutagenicity. Long-term exposure of low-content POPs will also have a certain impact on marine ecosystems and human beings. The contents of three typical persistent organic pollutants[polycyclic aromatic hydrocarbons (PAHs), organochlorine pesticides (OCPs), and polycyclic biphenyls (PCBs)] of surface sediments were analyzed using gas chromatography and mass spectrometry (GC-MS) to assess the pollution characteristics of persistent organic pollutants in Boao coastal waters. The distribution and source of persistent organic pollutants were analyzed in this study, and the ecological risk was assessed using three different methods:the effect interval low/median method (ERL/ERM), mean effect interval median quotient method (M-ERM-Q), and mean potential impact concentration quotient method (M-PEC-Q). The results indicated that the contents (measured by dry weight) of ΣPAHs, ΣOCPs, and ΣPCBs in the study area were 4.5-367.50, 3.99-175.30, and ND-2.89 ng·g-1, respectively, which were at a low level, and the overall distribution showed a trend of gradually increasing toward the sea. The results of POPs source analysis showed that the PAHs in the study area were mainly from the combustion of wood and coal. Among OCPs, the HCH was mainly from lindane, the historical land-based input had been completely degraded, and the DDT was mainly the traditional DDTs pesticides, with additional continuous DDT input. The PCBs were primarily pentachlorobiphenyls, which might have come from the release of paint on the bottom of the hull in the early stage of shipping and the peeling off of paint from old ships. The ecological risk assessment results showed that there was little difference among the assessment results of the three methods, which showed that only phenanthrene monomer of PAHs in the study area had a slight negative impact, and the DDT and the γ-HCH among PAHs would cause great ecological risk, whereas PCBs and other pollutants would not cause ecological risk. On the whole, the possibility of comprehensive ecological risk caused by the three pollutants was very small.

Influence of environmental heterogeneity on the distribution of micro-zooplankton community along the tropical coastal waters.

This study mainly focused on the water quality variability and distribution of micro-zooplankton (MZP) along the coastal waters of Tamil Nadu. Dendrogram analysis using water quality data categorized the study area into three regions: North (Chennai), Central (Puducherry), and South (Karaikal). The MZP consists of 40 ciliates and 8 dinoflagellates, with spirotrichea (52.4 %) significantly dominant, followed by dinophyceae (21.1 %), phyllopharyngea (14.7 %), and others (11.8 %). Paracyrtophoron tropicum, a new report in the coastal waters of India, was identified by comparing its molecular phylogeny (18S rRNA accession no: MT500569) to previously reported species. Statistical analysis revealed a positive correlation between P. tropicum abundance and water temperature, PO4, SiO4, TP, Chl-a, and Trichodesmium erythraeum, suggesting that they might not directly control the growth of P. tropicum but indirectly influence it via food availability, i.e., T. erythraeum. However, to understand these species interactions and ecological pathways, further long-term monitoring studies are required.

Source, transport, and fate of perfluoroalkyl acids (PFAAs) in turbid bay environments: Significant roles of suspended sediment and water column stratification.

The coastal area was the major region receiving pollution from land-based sources into the sea. Perfluoroalkyl acids (PFAAs) in famous bays had aroused wide concern, but the importance of underdeveloped or small bays with notable levels of PFAAs were often neglected. Moreover, the roles of suspended sediment (SPS) and water column stratification on PFAA behaviors were unclear. In this study, PFAAs distribution in multiphase-multilayer in four underdeveloped bays (two urban bays and two island bays) were investigated. The urban bays not only had higher PFAA contamination but also posed a greater threat of short-chain PFAAs in water-SPS-sediment system than the island bays. The major source of PFAAs in water and SPS was domestic sewage in urban bays and was rainfall-runoff in island bays. Water column stratification with higher PFAA partition in water-SPS system in the surface layer than in the bottom layer was only found in the urban bays due to the higher human activity intensity. These provided new perspectives for managing emerging contaminants and establishing water quality criteria in the turbid coastal environment. The key role of SPS as a carrier offered possibilities to accurately differentiate the effects of dissolved and particulate PFAAs on bioavailability.

Environmental concentrations, characteristics and risk assessment of microplastics in water and sediment along the Western Cape coastline, South Africa.

Plastic debris is accumulating in all environments globally and South Africa's poor waste management plan has led to an increase in plastic contamination throughout the country. Information about microplastics (MPs) in urban and rural coastal environments in South Africa is poor. The aim of this study was to determine coastal MP concentrations in water (particles/L) and sediment (particles/kg). Sampling took place in summer of 2020 during low tide at 14 sites, along the coast of the Western Cape, South Africa. MPs were extracted and analysed based on shape, color, size and polymer type (using an ATR-FTIR). An ecological risk assessment was done to assess the potential risks posed by MPs in all sample types. Sediment MP concentrations (185.07 ± 15.25 standard error particles/kg) were higher than water (1.33 ± 0.15 particles/L). Gordon's Bay (site 12) had the highest MP concentrations in sediment samples (360 ± 36.74 particles/kg), identifying harbors as the main source for MP contamination. Kalk Bay (site 9) displayed the highest concentration in water samples (4.97 ± 0.18 particles/L), suggesting that the source of MPs are from stormwater outfall pipes and human activities. Filaments were the most dominant MP shape (89%) for all samples, with black/grey (water) and transparent (sediment) being the most dominant colors (31% and 31% respectively). Dominant sizes were 1000-2000 µm in water and 2000-5000 µm in sediment. Polyethylene terephthalate (PET) (29%) was the most dominant polymer type recorded in water samples and natural fibres (mainly cotton) (32%) recorded in sediment. Based on the risk assessment, MPs recorded at Mouille Point (site 6) poses the greatest ecological risk associated with polymers. MP concentrations reported in this study provide a baseline for future studies along the Western Cape coastline of South Africa.

Development and application of diffusive gradients in thin films for in situ sampling of the organic UV filter 4-methylbenzylidene camphor (4-MBC) in waters.

4-Methylbenzylidene camphor (4-MBC), a typical organic UV filter (OUVF) in personal care products, is considered to be a potential endocrine disruptor due to its estrogenic activity and bioaccumulation. Although 4-MBC residues have been extensively identified in aquatic waters, little is known about their occurrence, levels, and potential risk in coastal waters. This study developed a reliable sampling approach, based on diffusive gradients in thin films (DGT) with XAD-2 as the binding agent, for monitoring 4-MBC in coastal waters. The diffusion coefficients of 4-MBC in freshwater and artificial seawater were 3.65 × 10-6 cm2/s and 3.83 × 10-6 cm2/s, respectively. XAD-2 binding gel showed rapid adsorption to 4-MBC. The accumulated masses of 4-MBC in XAD-2 DGT increased linearly with deployed time for 7 days in freshwater and seawater, which agreed well with theoretical predictions. The sampling performance was independent of ionic strength (0.0001-0.5 M), pH (4.0-8.5), and dissolved organic matter (0-20 mg/L). Field deployment in the river estuary and bathing beach showed that DGT-measured 4-MBC concentrations were consistent in comparison with grab sampling. Environmental risk assessment showed that 4-MBC may pose a medium risk to aquatic organisms based on computed risk quotient (RQ) values. Sewage discharge is the main source of 4-MBC risk, while the residue in recreation beaches contributes more significantly in summer. The established DGT sampling is suitable for seasonal monitoring, source identification, and risk assessment of 4-MBC in coastal waters.